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Check if your mobile device or phone is getting signal, if it does then it is already activated. As for the LTE, you need to be within the location where LTE is available. If your current location is not covered by the LTE network, your data connection will be either 3G, H, or H+ speed.
Needless to say, you have to have an LTE device to test it.
I'm saying this because I know a lot of people who apply for an LTE sim without an LTE device for the sake of having one (and in case they would have one in the near future).