Brochures are available in Globe Stores but you may already want to take a look at Globe myLifestyle Plan | Postpaid - Globe for better understanding of the Mobile phone plans they are currently offering and Postpaid | Help and Support for the requirements in having a postpaid plan.
Just a tip... it is better to get the plan in a Globe Store rather than online. The community members' experience would indicate that it is faster. As soon as you are approved, make sure to get a copy of the contract that you have signed as it is not standard practice that they give you a copy. It is important that you secure one as it would be the basis for future disputes. It would be hard to get a copy after that stage.